Ionothermal synthesis, crystal structure, topology and catalytic properties of heterometallic coordination polymers constructed from N-(phosphonomethyl) iminodiacetic acid.

Ionothermal synthesis , crystal structure , topology and catalytic property of heterometallic coordination polymers

A nanosized Gd6Ni3 cluster-based heterometallic coordination polymer.

A nanosized Gd6Ni3 cluster-based two-dimensional 3d-4f heterometallic coordination polymer has been synthesized under hydrothermal conditions using a mixture of H4PMIDA (H4PMIDA = N-(phosphonomethyl) iminodiacetic acid), Gd(ClO4)3 and Ni(CH3COO)2·4H2O. An electrical property investigation reveals that the coordination polymer exhibits a proton conductivity.

Syntheses, structures, and magnetic properties of heterometallic coordination polymers with carboxyphosphonate linkers†

Five heterometallic coordination polymers were synthesized utilizing the multifunctional carboxyphosphonate ligand N-(phosphonomethyl)iminodiacetic acid (H4PMIDA), N(CH2PO(OH)2)(CH2COOH)2, with a coordinating nitrogen atom and two carboxylate and one phosphonate groups. The compounds were characterized structurally and magnetically. [Cu2M2(PMIDA)2(H2O)6]$3H2O for M 1⁄4 Mn (1-CuMn), Co (2-CuCo),...

Synthesis, Characterization, and Crystal Structure of a New Coordination Polymer, {[Ba2(Hpydc)2(pydc)(H20)31.H20.(112P3110}n

The reaction of barium chloride with 2, 6-pyridinedicarboxylic acid in water led to the formation of a novelpolymeric complex formulated as {[Ba2(Hpydc)2(pydc)(H20)3].H20.(H2pydc)}.(I). The crystal structure of (I)was characterized by single crystal X-ray diffraction method. The complex was crystallized in the monoclinicsystem with space group P2/c, with four molecule in unit-cell, e.g Z=4. The...

Synthesis, Crystal Structure and Antibacterial Evaluation of Di-μ-chlorido-bis({2-[(4-methoxyphenyl)- iminomethyl]pyridine-κ2N,N']Mercury(II)

New coordination polymer of [HgLCl2]n (1) with HgCl2 and Schiff base bidentate ligand (4-methoxyphenyl) pyridine-2yl methyleneamine (L) was prepared and structurally characterized. In the 1D network structure of 1, the mecury (II) ion adopts an HgN2Cl3 distorted square pyramid geometry. In this complex, one of the chlorine acts as bridging ligand connecting two adjacent mercury(II) ions while, ...